Electroplating lithium transition metal oxides

نویسندگان

  • Huigang Zhang
  • Hailong Ning
  • John Busbee
  • Zihan Shen
  • Chadd Kiggins
  • Yuyan Hua
  • Janna Eaves
  • Jerome Davis
  • Tan Shi
  • Yu-Tsun Shao
  • Jian-Min Zuo
  • Xuhao Hong
  • Yanbin Chan
  • Shuangbao Wang
  • Peng Wang
  • Pengcheng Sun
  • Sheng Xu
  • Jinyun Liu
  • Paul V Braun
چکیده

Materials synthesis often provides opportunities for innovation. We demonstrate a general low-temperature (260°C) molten salt electrodeposition approach to directly electroplate the important lithium-ion (Li-ion) battery cathode materials LiCoO2, LiMn2O4, and Al-doped LiCoO2. The crystallinities and electrochemical capacities of the electroplated oxides are comparable to those of the powders synthesized at much higher temperatures (700° to 1000°C). This new growth method significantly broadens the scope of battery form factors and functionalities, enabling a variety of highly desirable battery properties, including high energy, high power, and unprecedented electrode flexibility.

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عنوان ژورنال:

دوره 3  شماره 

صفحات  -

تاریخ انتشار 2017